Sains Malaysiana 38(3):
313-320(2009)
Komposisi Geokimia Sedimen Pantai di Pulau Langkawi,
Kedah, Malaysia
(Geochemical Composition of Beach Sediment in Langkawi Island,
Kedah, Malaysia)
Wan Mohd Razi Idris*,
Sahibin Abdul Rahim, Zulfahmi Ali Rahman,
Tukimat Lihan, Azman Hashim &
Shahril Nizam Mohd Yusuf
Pusat Pengajian Sains Sekitaran dan Sumber Alam
Fakulti Sains dan Teknologi, Universiti Kebangsaan
Malaysia
43600, Bangi, Selangor. D. E.,
Malaysia
Received: 8 April 2008 / Accepted: 3 August 2008
ABSTRAK
Sebanyak 40 sampel sedimen pantai Pulau Langkawi telah dianalisis bagi
menentukan kepekatan kandungan logam berat Co, Pb, Ni, Cr, Zn dan Cu. Sampel
permukaan sedimen diambil di kawasan Pulau Dayang Bunting, Pulau Tuba dan Selat
Kuah. Parameter sedimen yang mempengaruhi pengkayaan logam berat seperti pH,
peratus kandungan bahan organik dan taburan saiz partikel sedimen juga
ditentukan. Data yang diperolehi menunjukkan kelimpahan kandungan logam berat
unsur Co, Pb, Ni, Cr, Zn, dan Cu di dalam sampel sedimen adalah masing-masing mempunyai
sela pada 13-75 µgg-1, 9-113 µgg-1, 3-57 µgg-1,
2-26 µgg-1, 8-69 µgg-1 dan 2-14 µgg-1. Nilai
pH dan kandungan bahan organik sedimen masing-masing mempunyai sela pada
3.95-8.39 dan 0.06-15.01%, manakala taburan saiz partikel didominasi oleh saiz
pasir iaitu melebihi 70%. Analisis korelasi bagi semua sampel menunjukkan
kelimpahan logam-logam berat di dalam sedimen dipengaruhi oleh kandungan bahan
organik, kelodak dan lempung, manakala korelasi di antara kandungan logam berat
menunjukkan hubungan positif signifikan dengan semua unsur pada paras melebihi
1%. Secara keseluruhan kepekatan kandungan logam berat Co dan Pb di dalam
sedimen adalah tinggi menunjukkan sekitarannya telah tercemar yang berpunca
daripada aktiviti pembangunan pesat di sebelah daratan ataupun aktiviti kelautan.
Kata
kunci: Geokimia; logam berat; Pulau Langkawi; sedimen
ABSTRACT
A total of 40 surface sediment samples collected from Pulau Langkawi namely
Pulau Daya Bunting, Pulau Tuba and Selat Kuah were analyzed to determine the heavy metal content
such as Co, Pb, Ni, Cr, Zn and Cu. Sediment parameters such as pH, organic
matter content and particle size distribution usually considered influential in
heavy metal enrichment were also determined. The abundance of heavy metals
namely Co, Pb, Ni, Cr, Zn and Cu in sediment samples ranged at 13-75 µgg-1,
9-113 µgg-1, 3-57 µgg-1, 2-26 µgg-1, 8-69 µgg-1 and 2-14 µgg-1 respectively. The values of pH and organic matter
content ranged at 3.95-8.39 and 0.06-15.01% respectively, whilst the particle
size distribution was dominated by sand with values of more 70%. Correlation
analysis showed that the organic matter content and the presence of silt and
clay minerals controlled the abundance of heavy metal in the sediment, whereas
heavy metal content had a significant positive correlation at above 1% level
with all elements. The Co and Pb heavy metal concentration were above the
critical level where potential toxicity in soil and sediment may occur. This
could be attributed to input of effluent from development activity in the inland
or from the sea.
Keywords: Geochemical; heavy
metal; Pulau Langkawi; sediment
RUJUKAN
Abdulla, H.H. 1966. A study on the Development of Podzol Profiles in Dovey Forest. Ph.D. Thesis,
University
of
Wales
.
Abdul Khalik Wood. 2002. Geokimia bahan kimia antropogenik dalam
persekitaran marin di Selat Melaka. Con. Shelf Res. 17 (10): 1207-1228.
Abu-Hilal, A.H. 1987. Distribution of trace elements in near shore surface sediments from the
Jordan Gulf of Agaba (
Red Sea
). Mar. Pollut. Bull. 18:190-193.
Acres, B.D., Bower, R.P., Borrough, P.A., Folland,
C.J., Kalsi, M.S., Thomas, P. & Wright, P.S. 1975. The Soils
of
Sabah
. Volume 1. Classification
and Description. Land
Resource Study No. 20, Land Resource Division, Ministry of Overseas
Development,
England
.
Allow, B.J. 1995. Heavy Metal in Soils. Inc. New
York. John Wiley and Son.
Angelidis, M.O. & Aloupi. M. 1995. Metal in sediments of
Rhodes Harbour
,
Greece
. Mar. Polluc. Bull 31: 273-276.
Arcer, F.C & Hodgson, I.H. 1987. Total and extractable trace elements contents of soil in
England
and
Wales
. Journal of Soil Science 39:421-432.
Atgin, R.S., El-Agha., O.Zararsiz., A.Kocates., A. Parlek, H & Tuncel G. 2000. Ivestigation of the sediments
pollution in
Izmir
Bay
: Trace elements. Spectrochimica Acta. Part B 55: 1151-1164.
Avery, B.W. & Bascomb, C.L. 1982. Soil Survey
Laboratory Methods. Soil Survey Technical
Monograph No. 6. Harpenden.
Birch, G.F., Robertson, E.,
Taylor
, S.E. &
McConchie, D.M. 1999. The use of sediments to detect human impact on the fluvial system. Environmental Geology 39 (9):
1015-1028.
Cobela-Garcie, A & Prego. 2003. Heavy sedimentary record in a Galician
Ria (NW Spain): Background values and recent contamination. Mar. Pollut. Bull 46: 1253-1262.
Donazzolo, J.C., O. hicki-Merlin, l. Menegazzovillurg & B. Paroni
1984. Heavy metal content and lithological properties of recent sediments in the Norten Adriati. Mar. Pollut. Bul 15: 192-201.
Fukue, M., Nakamura, T., Kato, Y & Yamasaki, S. 1999. Engineering of pollution from marine sediments. Environmental Science Technology 33: 2499-2504.
Garrison, T. 2005. Oceanography – an invitation to marine science. (eds 5).
London
.
Horowitz, A.J. & Elrick, K.A. 1987. The relationship of stream sediments surface area, grain saiz and
composition of trace elements chemistry. Applied Geochemistry 2:437-452.
Ismail, A.
1993. Heavy
Metal Concentration in Sediments of Bintulu, Malaysian. Marine
Pollution Bulletin 26:706-707.
Kabata-Pendias, A. and Pendias, H. 1992. Trace elements in soil and plants (2nd ed.). CRC Press,
Boca Raton
,
Florida
.
Laxen, D.P. H. 1983. The Chemistry of Metal Pollution in Water. In: Pollution causes, effects and control (Ed),
Roy
. M. Horrison, The Royal Society of Chemistry,
London
:
104-112.
Martincic, D.Z. Kwokal, M. Stoeppler &
M. Branica. 1985. Trace metal in the Sibenik auqatorium. P-3 sediment concentration of Zn, Cd, Pb, Cu and Hg analyzed in the
1983/84 period. Rapp.
Int.
Me.
Medit. 115-116.
Metson,
A.J. 1956. Methods of chemical analysis for soil survey samples. Bull. N.Z. Dept. Scient.
Ind.
Res. No.
12.
Muohi, A.W., Onyari, J.M., Omondi, J.G.
& Mavuti, K.M. 2003. Heavy metal distribution in surface sediments from
Mutwapa and Shirazi creeks, Kenyan, Coastal. Bulletin of Environmental Contamination and Toxicology 70: 1220-1227.
Roslan
I.
, Samsuri, A.W., Zauyah S. & Fauziah C.I. 2005. Heavy
metals in the sediment of the estuarine, Kuala Sepetang mangrove forest, Perak. Proc. Soil Sci. Malaysian: 215-217.
Schrauzer, G.N. 1991. Cobalt. In: Metals
and Their Compounds in the Environment: Occurrence, Analysis, and Biological
Relevance, VCH (1991), edited by Merian E.. pp.
879–892.
Schulin, R., Geiger, G., & Furrer, G. 1995. Heavy metal retention by soil organic matter under changing
environmental conditions. In Biodynamics of pollutants in soils and
sediments – Risk assessment of delayed and non-linear responses, edited by
Salomons, W. & Sigliani, W.M (pp. 53-85).
Berlin Heidelberg New York: Springer.
Wedepohl,
K.H. 1960. Spurenanalytische untersuchungen au tiefsectonen
aus dem
Atlantic
. Geochim. Cosmochine. Acta 18:200-231.
White, A.T. 1988.
Marine
Parks
and Reserves, Management for coastal environments in
Southeast Asia
. ICLARM, Educ.
Ser. 2. International center for Living Aquatic Resources
Management,
Manila
,
Philippines
, 36 pp.
Withman, G.T. & Forstner, U.
1979. Metal enrichment sediments in inland water-The Hartbeespoort Dam. Water AS 1: 76-82.
Yusof. A.M., Yanta,
N.F. & Wood A.K.H. 2004. The use of bivalve as
bio-indicator in the assessment of marine pollution along a coastal area. J. Radioanal. Nucl. Chem 25(1):119-127.
*Corresponding author: email: razi@ukm.my
|