Sains Malaysiana 40(8)(2011): 827–830

 

Vertical Variation of Lead, Copper and Manganese in Core Sediments Collected

From Tanjung Lumpur Mangrove Forest, Pahang, Malaysia

(Kepelbagaian Menegak Plumbum, Kuprum dan Manganese di Dalam Teras Sedimen Hutan Paya Bakau Tanjung Lumpur, Pahang, Malaysia)

 

B.Y. Kamaruzzaman*, M.Y. Nurul Nadia & M.S. Noor Azhar

Institute of Oceanography and Maritime Studies , International Islamic University Malaysia

25200 Kuantan, Pahang, Malaysia

 

S. Shahbudin

Faculty of Maritime Studies and Marine Science, Universiti Malaysia Terengganu

21030 Kuala Terengganu, Terengganu, Malaysia

 

B. Joseph

Institute of Oceanography, Universiti Malaysia Terengganu, 21030 Kuala Terengganu

Terengganu, Malaysia

 

Received: 9 February 2010 / Accepted: 10 November 2010

 

 

ABSTRACT

Two core sediment samples collected from Tanjung Lumpur mangrove forest were analysed for lead, copper and manganese using the sensitive Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). The average concentrations of Pb, Cu, and Mn in core samples were 36.28±7.04 μg/g dry weights, 50.17±5.84 μg/g dry weights, and 110.41±14.48 μg/g dry weights, respectively. From the calculated enrichment factors (EF), only Mn was considered to be predominantly terrigeneous in origin, while Pb and Cu have slightly higher EF values which were related to anthropogenic input.

 

Keywords: Cu; enrichment factor; Mn; Pb; Tanjung Lumpur mangrove forest

 

ABSTRAK

Dua sampel teras yang diperoleh dari hutan paya bakau Tanjung Lumpur dianalisis untuk plumbum , kuprum dan mangan dengan menggunakan peralatan sensitif Spekrometri Jisim - Plasma Gandingan Induktif (ICP-MS). Purata kepekatan Pb, Cu dan Mn adalah masing-masing 36.28±7.04 μg/g berat kering, 50.17±5.84 μg/g berat kering, and 110.41±14.48 μg/g berat kering. Daripada pengiraan faktor pengkayaan (EF), Mn didapati dominan kepada sumber semula jadi, manakala Pb dan Cu yang mempunyai nilai EF yang lebih tinggi berkemungkinan mempunyai sumber hubungan dengan sumber antropogenik.

 

Kata kunci: Cu; faktor pengayaan; hutan paya bakau Tanjung Lumpur; Mn; Pb;

REFERENCES

 

Aller, R.C. 1982. The effects of microbenthos on chemical properties of marine sediment and overlying water. In Animal-Sediment Relations. McCall, P. L. and Tevesz, M. S. J. (eds.) 53-102. Plenum Press, New York.

Berner, R.A. 1980. Early Diagenesis: A Theoretical Approach. Princeton: Princeton University Press,

Francois, R., Emerson, S. & Huested, S.S. 1993. Glacial/interglacial changes in sediment rain rate in the SW Indian sector of sunAntartic waters as recorded by 231Th, 231Pa, U and δ15 N. Paleocanography 8: 611-629.

Froelich, P.N., Klinkhammer, G.P., Bender, M.L., Luedtke, N.A., Heath, G.R., Cullen, D., Dauphin, P., Hammond, D., Hartman, B. & Maynard, V. 1979. Early oxidation of organic matter in pelagic sediments of the eastern equatorial Atlantic: Suboxic diagenesis. Geochim. Cosmochim. Acta 43: 1075-1090.

Hartman, M., Muller, P.J., Suess, E. & Van Der Weijden, C.H. 1979. Chemistry of late quarternary sediments and their interstial waters from the NW African continental margin. Meteor 24: 1-67.

Kamaruzzaman, K.Y. 1994. A study of some physico-chemical parameters in the estuarine system of Chukai-Kemaman rivers, Terengganu. M. Sc. Thesis. Universiti Putra Malaysia, 222 pp. (Unpublished)

Kamaruzzaman, B.Y., Jamil, T. & Hasrizal, S. 2004. Organic Carbon in Sediments and Particulate Organic Carbon in water of the Chukai-Kemaman Estuarine System. Journal of BioScience 15(1): 89-97.

Kamaruzzaman, B.Y., Ong, M.C. & Willison, K.Y.S. 2005. Taburan Kepekatan Unsur Kimia Di Dalam Teras Sediment Di Hutan Paya Bakau, Terengganu. Malaysian Journal of Analytical Sciences 9(1): 111-115.

Kamaruzzaman, B.Y., Shazili, N.A.M., Mohd Lokman, H. & Sulong, I. 2002. Geochemistry of some heavy metals as recorded in the sediment of the Kuala Kemaman Mangrove Forests, Terengganu, Malaysia. Oriental Journal of Chemistry 18(1): 7-14.

Kamaruzzaman, B.Y., Suhaimi, H., Teh, E.K., Leong, H.F., Soon, K.H. & Chong, K.Y. 2001. The determination of 230Th in the sediments: Sedimentation in the mangrove Forests of Pulau Sekeping, Kemaman, Terengganu. Journal of Ultra Scientist of Physical Sciences 13(2): 239-245.

Kremling, K. & Streu, P. 1993. Saharan dust influence trace element fluxes in deep North Atlantic subtropical waters. Deep Sea Research 40: 1155-1168.

Lacerda, L.D. & Abrao, J.J. 1984. Heavy metals accumulation by mangrove and salt marsh intertidal sediments. Rev. Bras. Bot. 7: 49-52.

Leong, H.F. 2001. Geochemical proxy for mangrove forest of Pulau Sekeping, Kemaman. Final Year report, Bachelor Science (Marine Science), Faculty of Applied Science and Technology, Universiti Putra Malaysia Terengganu. 71p. (Unpublished)

Macdonald, R.W., Macdonald, D.M., O’Brien, M.C. & Gobeil, C. 1991. Accumulution of heavy metals (Pb, Zn, Cu Cd), carbon and nitrogen in sediments from strait of Georgia, B.C., Canada. Marine Chemistry 34: 109-135.

Manson, B. & Moore, C.B. 1982. Principles of Chemistry, 4th Edition. New York: J. Willey and Sons.

Molinari, E., Guerzoni, S. & Rampazzo, G. 1993. Contribution of Saharan dust to the central Mediterranean Basin. Geological Society of America, special paper 284: 303-312.

Nittrouer, C.A., Sternberg, R.W., Carpenter, R. & Bennett, J.T. 1979. The use of 210Pb geochronology as a sedimentological tool: application to the Washington continental shelf. Marine Geology 3: 297-316.

Noriki, S.K., Nakanishi, T., Fukawa, M., Uematsu, T., Uchida & S. Tsunogai 1980. Use of a teflon vessel for the decomposition followed by the determination of chemical contituents of various marine samples. Bull. Fac. Fish, Hokkaido Univ. 31: 354-465.

Prohic, E. & Kniewald, G. 1987. Heavy metal distribution in recent sediments of the Krka River estuary – an example of sequential extraction analysis. Marine Chemistry 22: 279-297.

Ridgway, I.M. & Price, N.B. 1987. Geochemical associations and post depositional mobility of heavy metals in coastal sediments: Loch Etive, Scotland. Marine Chemistry 21: 229-248.

Silva, C.A.R., Lacerda, L.D. & Rezende, C.E. 1990. Heavy metal reservoirs in a red mangrove forest. Biotropica 22: 339-345.

Skei, J. & Paus, P.E. 1979. Surface metal enrichment and partitioning of metals in a dated sediment core from a Norwegian fjord, Geochim. Cosmochim. Acta. 43: 239-246.

Tam, N.F.Y. & Yao, M.W.Y. 1998. Normalization and heavy metal contamination in mangrove sediments. Science of the Total Environment 216: 33-39.

Thomson, J., Wallace, H.E., Colley, S. & Toole, J. 1990. Authigenic uranium in Atlantic sediments of last glacial stage – a diagenetic phenomenon. Earth Planet. Sci. Lett. 98: 222-229.

Wangersky, P.J. 1962. Sedimentation in three carbonate cores. Journal Geol. 70: 364-375.

 

*Corresponding author; email: kama@iiu.edu.my

 

 

 

previous