Sains Malaysiana 43(6)(2014):
923–927
Structural
Properties of Zinc Oxide Thin Films Deposited on Various Substrates
(Ciri
Struktur Filem Nipis Zink Oksida yang Dimendapkan di atas Substrat Berlainan)
C.G. CHING*, P.K. OOI, S.S. NG, Z. HASSAN, H. ABU HASSAN
& M.J. ABDULLAH
Nano-Optoelectronics
Research and Technology Laboratory, School of Physics, Universiti Sains
Malaysia, 11800 Penang, Malaysia
Received: 2
March 2013/Accepted: 26 January 2014
ABSTRACT
In this work, the structural properties of radio
frequency sputtering-grown zinc oxide (ZnO) thin films on sapphire (Al2O3), gallium arsenide
(GaAs) and n-type silicon (Si) substrates were characterized. Scanning electron
microscopy was employed to study the surface morphology of the samples. X-ray diffraction
(XRD) measurements were also performed to obtain the structural information of
the samples. The XRD results showed that the ZnO layers grown on different
substrates have similar lattice constant (c) values, which were used to
calculate the strain percentages of the ZnO thin films. The surface
morphologies of the ZnO thin films indicated the formation of a granular
surface when ZnO is deposited on n-type Si(100) and Si(111) substrates.
Meanwhile, a leaf-like surface is obtained when ZnO is deposited on GaAs and Al2O3 substrates. The
results showed that the ZnO thin film grown on n-type Si(100) has the best
quality among all the samples.
Keywords: Gallium
arsenide; sapphire; silicon; XRD; zinc oxide
ABSTRAK
Dalam kajian ini, pencirian struktur filem nipis
zink oksida (ZnO) yang ditumbuhkan dengan teknik percikan frekuensi
radio ke atas substrat nilam (Al2O3), galium arsenik (GaAs)
dan silikon (Si) jenis-n telah dijalankan. Mikroskop elektron imbasan
digunakan untuk memperoleh morfologi permukaan sampel manakala pembelauan
sinar-X (XRD) pula digunakan untuk memperoleh maklumat struktur
bagi sampel. Keputusan XRD menunjukkan ZnO yang ditumbuhkan di atas
substrat berlainan mempunyai pemalar kekisi paksi-c yang hampir
sama. Nilai pemalar kekisi paksi-c yang diperoleh digunakan untuk
menghitung peratusan ketegangan filem nipis ZnO. Morfologi permukaan
filem nipis ZnO menunjukkan pembentukan permukaan bercorak butiran
apablia ZnO ditumbuhkan ke atas substrat Si(100) dan Si(111) jenis-n
dan permukaan bercorak daun diperoleh apabila ZnO ditumbuhkan ke
atas substrat GaAs dan Al2O3. Akhirnya, keputusan XRD menunjukkan bahawa filem
nipis yang ditumbuhkan ke atas Si(100) jenis-n mempunyai kualiti
kristal yang terbaik antara sampel.
Kata kunci:
Galium arsenida; nilam; pembelauan sinar-X; silikon; zink oksida
REFERENCES
Ashrafi,
A.B.M.A., Zhang, B.P., Binh, N.T., Wakatsuki, K. & Segawa, Y. 2005. Biaxial
strain effect in exciton resonance energies of epitaxial ZnO layers grown on
6H–SiC substrates. J. Cryst. Growth 275: e2439-e2443.
Ashrafi,
A.B.M.A., Zhang, B.P., Nguyen, B.T. & Segawa, Y. 2004. High-quality ZnO
layers grown on 6H-SiC substrates. Jpn. J. Appl. Phys. 43: 1114-1117.
Bie,
L.J., Yan, X.N., Yin, J., Duan, Y.Q. & Yuan, Z.H. 2007. Nanopillar ZnO gas
sensor for hydrogen and ethanol. Sensor Actuat. B-Chem. 126: 604-608.
Chang,
R.C., Chu, S.Y., Lo, K.Y., Lo, S.C. & Huang, Y.R. 2005. Physical and
structural properties of RF magnetron sputtered ZnO films. Integr.
Ferroelectr. 69: 43-53.
Choudhury,
N. & Sarma, B.K. 2009. Structural characterization of lead sulfide thin
films by means of X-ray line profile analysis. Bull. Mater. Sci. 32:
43-47.
Hung,
S.C., Huang, P.J., Chan, C.E., Uen, W.Y., Ren, F., Pearton, S.J., Yang, T.N.,
Chiang, C.C., Lan, S.M. & Chi, G.C. 2008. Nanostructured surface morphology
of ZnO grown on p-type GaN and Si by metal organic chemical vapor deposition. Appl.
Surf. Sci. 255: 3016-3018.
Iwata,
K., Fons, P., Yamada, A., Matsubara, K. & Niki, S. 2000. Nitrogen-induced
defects in ZnO: N grown on sapphire substrate by gas source MBE. J. Cryst.
Growth 209: 526-531.
Jeon,
Y.S., Kim, D.M. & Hwang, K.S. 2007. Epitaxially grown ZnO thin films on
6H-SiC(0001) substrates prepared by spin coating-pyrolysis. Appl. Surf. Sci. 253: 7016-7018.
Kang,
M.I., Kim, S.W., Kim, Y.G. & Ryu, J.W. 2010. Dependence of the optical
anisotropy of ZnO thin films on the structural properties. J. Korean Phys.
Soc. 57: 389-394.
Kim, E.H., Lee,
D.H., Chung, B.H., Kim, H.S., Kim, Y. & Noh, S.J. 2007. Low-temperature
growth of ZnO thin films by atomic layer deposition. J. Korean Phys. Soc. 50:
1716-1718.
Kim, J.B., Byun,
D., Ie, S.Y., Park, D.H., Choi, W.K., Choi, J.W. & Angadi, B. 2008.
Cu-doped ZnO-based p–n hetero-junction light emitting diode. Semicond.
Sci. Tech. 23: 095004.
Kumar, M., Kar,
J.P., Kim, I.S., Choi, S.Y. & Myoung, J.M. 2010. Growth of p-type ZnO thin
film on n-type silicon substrate and its application as hybrid homojunction. Curr.
Appl. Phys. 11: 65-69.
Lee, J.H., Kim,
Y.Y., Cho, H.K. & Lee, J.Y. 2009. Microstructural characteristics and
crystallographic evolutions of Ga-doped ZnO films grown on sapphire substrates
at high temperatures by RF magnetron sputtering. J. Cryst. Growth 311:
4641- 4646.
Ma, Y., Du, G.,
Yin, J., Yang, T. & Zhang, Y. 2005. Structural and optoelectrical
properties of ZnO thin films deposited on GaAs substrate by metal-organic
chemical vapour deposition (MOCVD). Semicond. Sci. Technol. 20:
1198-1202.
Matsumoto, T.,
Nishimura, K., Nabetani, Y. & Kato, T. 2004. MBE growth and optical
properties of ZnO on GaAs(111) substrates. Phys. Stat. Sol. (b) 241:
591-594.
Ryu, Y.R., Lee,
T.S., Lubguban, J.A., White, H.W., Park, Y.S. & Youn, C.J. 2005. ZnO
devices: Photodiodes and p-type field-effect transistors. Appl. Phys. Lett. 87:
153504.
Schuler, L.P.,
Alkaisi, M.M., Miller, P., Reeves, R.J. & Markwitz, A. 2005. Comparison of
DC and RF sputtered zinc oxide films with post-annealing and dry etching and
effect on crystal composition. Jpn. J. Appl. Phys. 44: 7555-7560.
Talla, K.,
Dangbégnon, J.K., Wagener, M.C. & Botha, J.R. 2010. ZnO grown by metal
organic chemical vapor deposition: Effect of substrate on optical and
structural properties. South African Institute of Electrical Engineers 101:
37-41.
Yang, X.L.,
Chen, N.F., Yin, Z.G., Zhang, X.W., Li, Y., You, J.B., Wang, Y., Dong, J.J.,
Cui, M., Gao, Y., Huang, T.M., Chen, X.F. & Wang, Y.S. 2010. Epitaxial
growth of ZnO on GaN/ sapphire substrate by radio-frequency magnetron
sputtering. J. Semicond. 31: 093001.
*Corresponding
author; email: chingchinguan@gmail.com
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