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Sains Malaysiana 45(10)(2016):
1461–1468 Biodiesel from Thevetia peruviana
Seed Oil with Dimethyl Carbonate Using as an Active Catalyst Potassium-Methoxide (Biodiesel daripada Minyak Biji Thevetia
peruviana dengan Dimetil Karbonat Digunakan sebagai Pemangkin
Aktif Kalium-Metoksid) BALAJI M.
PANCHAL1*,
SANJAY
A.
DESHMUKH2
& MUNISH R.
SHARMA2 1Department of Biochemistry,
Dr. Babasaheb Ambedkar Marathawada University, Aurangabad, Maharashtra
431004, India 2Nurture Earth Research
and Development Pvt. Ltd., MIT, Beed Bypass Road, Aurangabad 431028,
India Received: 20 May
2015/Accepted: 18 February 2016 ABSTRACT The transesterification of
Thevetia
peruviana seed oil with dimethyl carbonate (DMC)
for preparing biodiesel has been studied using as an active catalyst
potassium-methoxide (KOCH3). The effects of reaction conditions:
Molar
ratio of dimethyl carbonate to Thevetia peruviana seed
oil, catalyst concentration, reaction time and agitation speed
on dimethyl esters (DMC-Tp-BioDs) yield were investigated. The highest DMC-Tp-BioDs
yield could reach 97.1% at refluxing temperature for 90 min with
molar ratio of DMC-to-oil
5:1 and 2.0% w/w KOCH3 (based on oil weight). The fuel properties
of the produced DMC-Tp-BioDs were compared with the ASTM
D6751-02 biodiesel standard. Keywords: Biodiesel; dimethyl
carbonate; oil extraction; optimization conditions; potassium
methoxide; Thevetia peruviana seed oil ABSTRAK Pengesteran trans daripada
minyak biji Thevetia peruviana dengan dimetil karbonat (DMC)
untuk menyediakan biodiesel telah dikaji digunakan sebagai suatu
pemangkin aktif kalium-metoksid (KOCH3). Kesan tindak balas keadaan: hasil
nisbah molar dimetil karbonat minyak biji Thevetia peruviana,
pemangkin kepekatan, masa reaksi dan kelajuan pergerakan dimetil
ester (DMC-Tp-BioDs)
dikaji. Kadar hasil tertinggi DMC-Tp-BioDs boleh mencapai 97.1%
pada perefluksan suhu untuk 90 min dengan nisbah molar DMC-kepada-minyak
5:1 dan 2.0% w/w KOCH3 (berdasarkan berat minyak). Sifat bahan
api yang dihasilkan DMC-Tp-BioDs dibandingkan dengan piawaian
ASTM D6751-02 biodiesel. Kata kunci: Biodiesel; kalium metoksid; karbonat dimetil; keadaan
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