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Sains Malaysiana 51(6)(2022):
http://doi.org/10.17576/jsm-2022-5106-13
Graphene Oxide
Immobilized Binuclear Biomimetic Catalyst for Triclosan Degradation in Aqueous Solution
(Pemangkin Biomimetik Binukleus Grafin Oksida Tidak Bergerak
kepada Degradasi Triklosan dalam Larutan Akues)
XUE-FEI
ZHOU1,2,* & SHUN-YANG CHEN1
1Fujian Provincial Key Laboratory of Marine
Ecological Conservation and Restoration, Third Institute
of Oceanography, Ministry of Natural Resources, 361005 Xiamen, China
2Faculty of Chemical Engineering, Kunming
University of Science and Technology, 650500 Kunming, China
Received: 21 June
2021/Accepted: 1 November 2021
Abstract
Biomimetic
catalysts, Zn(salen), Zn(Phe-TPP), ZnPSC6 and graphene oxide (GO) immobilized ZnPSC6 (ZnPSC6/GO), were fabricated.
These biomimetic catalysts were tested for catalytic decomposition of emerging contaminant triclosan (TCS). Catalysts were characterized
using Brunauer-Emmett-Teller (BET), X-ray Diffraction (XRD), Fourier Transform infrared (FTIR), and
Raman spectra. The reaction processes were studied using HPLC, and the treated
solutions were tested based on total carbon content (TCC) analysis and toxicity
analysis. The impacts of catalysts on TCS
degradation were investigated through testing
removal efficiency, total carbon content (TCC) and ecotoxicity. The results showed that ZnPSC6/GO displayed high activity due to salen-porphyrin binuclear active sites and
immobilization into GO compared with Zn(salen), Zn(Phe-TPP), and ZnPSC6. Finally, the reaction conditions of TCS oxidation catalyzed by ZnPSC6/GO has been preliminarily discussed. In these conditions, high removal efficiency was observed (96.7%; [ZnPSC6/GO] = 3.0
ppm, [TCS] = 0.02 mmol/L, [H2O2] = 0.60 mmol/L, T = 70 °C, t = 90 min, pH = 8).
Keywords:
Biomimetic catalysis; degradation; salen-porphyrin complex; TCS
Abstrak
Pemangkin
biomimetik, Zn(salen), Zn(Phe-TPP), ZnPSC6 dan grafin oksida (GO)
tidak bergerak ZnPSC6 (ZnPSC6/GO) telah dihasilkan.
Pemangkin biomimetik ini telah diuji untuk penguraian pemangkin bagi triklosan
cemaran memuncul (TCS). Pemangkin tersebut telah dicirikan menggunakan
Brunauer-Emmett-Teller (BET), pembelauan Sinar-X (XRD), transformasi Fourier
inframerah (FTIR) dan spektrum Raman. Proses tindak balas telah dikaji
menggunakan HPLC dan larutan yang telah dirawat diuji berdasarkan analisis
jumlah kandungan karbon (TCC) dan analisis ketoksikan. Kesan pemangkin pada
degradasi TCS telah dikaji melalui ujian kecekapan penyingkiran, jumlah
kandungan karbon (TCC) dan ekoketoksikan. Keputusan menunjukkan bahawa ZnPSC6/GO
menunjukkan aktiviti yang tinggi disebabkan oleh tapak aktif binukleus
salen-porfirin dan imobilisasi ke dalam GO berbanding dengan Zn(salen),
Zn(Phe-TPP) dan ZnPSC6. Akhirnya, keadaan tindak balas pengoksidaan
TCS yang dimangkinkan oleh ZnPSC6/GO telah dibincangkan terlebih
dahulu. Oleh itu, kecekapan penyingkiran tertinggi telah diperhatikan (96.7%;
[ZnPSC6/GO] = 3.0 ppm, [TCS] = 0.02 mmol/L, [H2O2] = 0.60 mmol/L, T
= 70 °C, t = 90 min, pH = 8).
Kata kunci:
Degradasi; pemangkin biomimetik; salen-porfirin kompleks; TCS
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*Corresponding
author; email: lgdx602@sina.com
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