Sains Ma1aysiana 26(2): 43-51(1997)                                                                                            Sains hayat/

                                                                                                                                                                 Life Sciences

 

Effect of Irradiation on Lipid Characteristic of Plant Nuts

 

 

Anwar Ahmad Sattar

Nuclear Institute for Food and Agriculture (NIFA) Peshawar

 

Altaf Hussain

Nuclear Institute for Agriculture and Biology

Faisalabad, Pakistan

 

Mohammad Zafar Iqbal

of Chemistry University Of Punjab

Lahore, Pakistan

 

 

ABSTRACT

 

Different plant nuts were irradiated with gamma rays to dose levels of 0.5, 1.0 and 1.5 kGy. Total lipids of the treated and untreated samples of plant nuts such as almond, peanut, pinenut, walnut and stones of apricot were extracted with petroleum benzene. The esterified lipids were analyzed for their fatty acid composition by gas chromatography (CC) whereas the extracted oils were tested for other physical characteristics like peroxide, iodine, anisidine and free fatty acid (FFA) values. The cc analysis showed that irradiation treatment of 1.5 kGy exhibited almost negligible effect on the composition of fatty acids. The peroxide, anisidine and FFA values were higher in the irradiated samples than untreated controls. It was also observed that these effects were increased by increasing the irradiation dose from 0.5 to 1.5 kGy but a reverse trend was noted in the case of iodine value in each case.

 

ABSTRAK

 

Beberapa jenis kacang telah disinari dengan sinar gamma pada takaran 0.5, 1.0 dan 1.5 kGy. Jumlah kandungan lemak dalam kacang seperti almon, kacang tanah, kacang pine, walnut dan biji aprikot yang tidak dan telah disinari telah diekstrak dengan menggunakan eter petroleum. Kandungan asid lemak pada lemak terester telah dianalisis dengan menggunakan kromatografi gas sedangkan minyak yang telah diekstrak telah diuji sifat­sifat fizikal seperti nilai peroksida, iodina, anisidina dan asid lemak bebas. Analisis kromatografi gas menunjukkan bahawa sinaran 1.5 kGy tidak memberi kesan yang bermakna terhadap kandungan asid-asid lemak. Nilai peroksida, anisidina dan asid lemak bebas adalah tinggi dalam kacang yang disinari. Telah juga diperhatikan bahawa kesan-kesan ini meningkat dengan peningkatan taka ran daripada 0.5 kepada 1.5 kGy tetapi kesan yang sebaliknya diperhatikan pada nilai iodina.

 

 

RUJUKAN/REFERENCES

 

Ahmad, A, Sattar, A & Iqbal, M. Z. 1995. Detection of irradiated dried fruits and plant nuts by chemiluminescence measurements. Pak. J. Food Sci. 5: 23-25.

Ahmad, T., Atta, S. & Sattar, A 1993. Stability of edible oil in relation to irradiation and antioxidants. Sci. Intern. (Lahore), Proc. 2nd All Pak. Sci Conf. ahore Dec. 26-30, 183-184.

Bogl, K. W. 1990. Methods for identification of irradiated food. Radiat. Phys. Chem. 35: 301-310.

Dubravic, M.F. & Nawar, W. W. 1968. Radiolysis of lipids. Mode of cleavage in simple triglycerides. A.D.CS. 45: 656-660.

IAEA. 1991. Analytical detection methods for irradiated food. IAEA TECDOC-587 March, pp.8.     

Khan, H M, Bhatti, I.A, Sattar, A, & Ahmad, A 1993. Evaluation of different techniques for the detection of irradiated food stuffs. Sci. Intern. (Lahore) Proc. 2nd All Pak. Sci Conf. Lahore Dec. 26-30, 187-188    

Khan, H M, Bhatti, LA., Sattar, A., Ahmad, T. & Hussain, A 1994. Identification of gamma irradiated spices by determining radiation induced chemical changes. Sci. Intern. (Lahore) 7: 239-40.

Khan, H.M & Delincee, H. 1995. Detection of irradiation treatment of dates using thermoluminescence of mineral contaminants. Rad. Phys. Chem. 46: 717-20.

Kim, M. M. & Ku, Y. 1990. A gas chromatographic method for identification of irradiated frog legs. Radiat. Phys. Chem. 35: 337-341.

Little, J. M. & Hills, F. J. 1972. Statistical methods in analytical research. Agric. Extension. Davis, USA: Univ. California.

Nawar, W. W. 1978. Reaction mechanism in radiolysis of fat. J. Agric. Food Chem. 26: 21-25.

PORIM. 1993. PORIM test methods. Palm Oil Research Institute of Malaysia, Kuala Lumpur.

Sattar, A, Delincee, H. & Diehl, I. F. 1987a: Detection of gamma irradiated pepper and papain by chemiluminescence. Radiat. Phys. Chem. 29: 215-221.

Sattar, A, Khan, D., Jan, M., Ahmad, A & Khan, L 1987b. Effect of gamma irradiation on peroxidation of dry nut oils and fats. Sarhad J. Agric. 3: 61-6.

Sattar, A, Mohammad, J., Saleem, A, Jan, M. & Ahmad, A 1990. Effect of fluorescent light gamma radiation and packages on oxidative deterioration of dry nuts. Sarhad J. Agric. 6: 235-40.

Sattar, A., Ahmad, T. & Atta, S. 1995a. Stability of palm and palm kernel to gamma and visible light irradiation. Proc. PORIM Intern. Palm oil Congress update and vision, Edt. Basiron et aI, 98-99.

Sattar, A., Ahmad, A., Atta S. & Ahmad T. 1995b. Development of detection methods and label dosimeters for gamma irradiated dried fruits and tree nuts. In Impact of food research on new product development. Edt. R. Ali, P.J. Barlow and J. R. Whitaker. Proc. 2nd Inter. Conf. Uni. Karachi Pakistan, 97-104.

Shehata, A. Y., Deman, J. M. & Alexander, J.e. 1970. A simple and rapid method for the preparation of methyl esters of fats in miligram amounts for gas chromatog­raphy. Can. Inst. Food Sci. Technol. J. 3: 85-89.

Swallow, A. J. 1990. Need and role of identification of irradiated food. Radiat. Phys. Chem. 35: 311-316.

Vajidi, M. & Nawar, W. W. 1978. Identification of radiolytic compounds from beef. AOCS 56: 611-615.

 

 

 

previous