Sains
Malaysiana 41(4)(2012): 453-458
Sifat Magnet, Mikrostruktur dan
Morfologi Komposit Getah Asli
Termoplastik Berpengisi Ferit NiZn/MWNT
(Magnetic
Properties, Microstructure and Morphology of Thermoplastic Natural
Rubber
Composite Reinforced with NiZn Ferrite/MWNT)
Lih-Jiun
Yu*, Sahrim Hj. Ahmad, Ing Kong, Sivanesan Appadu
&
Moayad Husein Flaifel
Pusat
Pengajian Fizik Gunaan, Fakulti Sains dan Teknologi, Universiti Kebangsaan
Malaysia
43600
Bangi, Selangor D. E., Malaysia.
Received:
7 June 2011 / Accepted: 24 August 2011
ABSTRACT
NiZn
ferrite and carbon nanotube were blended with TPNR according to the mixing
ratio 1:1. Filler addition effects on magnetic properties, microstructure, and
morphology of the nanocomposite were studied. Saturation magnetization and coercive
force of nanocomposites were found depend on the filler loading in the matrix.
The interaction between both fillers in the TPNR matrix was found to effect on
the magnetic properties. The hybrid fillers (NiZn ferrite and carbon nanotube)
were distributed homogenous in the thermoplastic natural rubber matrix. The
crystallinity of semi-amorphous polypropylene was found to decreases, opposite
to the increment of fillers when the fillers content was increased.
Keywords:
Hybrid composite; magnetic properties; thermoplastic natural rubber
ABSTRAK
Ferit
NiZn dan nanotiub karbon diadunkan ke dalam getah asli termoplastik mengikut
nisbah campuran 1:1. Kesan penambahan pengisi ke atas sifat magnet, struktur
dan morfologi nanokomposit dikaji. Dua parameter magnet, iaitu pemagnetan
tepuan dan daya koersif nanokomposit didapati bergantung kepada penambahan
pengisi dalam matriks. Interaksi antara kedua-dua pengisi dalam matriks TPNR
juga mempengaruh sifat magnet. Pengisi hibrid (ferit NiZn dan nanotiub karbon)
bertabur sekata dalam matriks termoplastik getah asli. Kehabluran semi-amorfus
fasa polipropilena didapati berlawanan dengan peningkatan kehabluran pengisi
apabila kandungan pengisi bertambah
.
Kata
kunci: Komposit getah asli termoplastik; komposit hybrid; sifat magnet
REFERENCES
Alariqi,
S.A.S., Pratheep Kumar, A., Rao, B.S.M. & Singh, R.P. 2009. Effect of dose
rate on crystallinity and morphological changes of sterilized biomedical
polypropylene. Polymer Degradation and Stability 94(2): 272-277.
Castanon,
S.D., Farloh-Gandarilla, J.C., Munoz-Sandoval, E. & Terrones, M. 2008.
Vibration sample magnetometry, a good tool for the study of nanomagnetic
inclusions. Superlattices and Microstructures 43: 482-486.
Guo,
Z., Park, S. & Thomas Hahn, H. 2007. Magnetic and electromagnetic
evalulation of the iron nanoparticle filled polyurethane nanocomposites. Journal
of Applied Physics 101(9) 511-513.
Low,
S.P., Ahmad, A., Hamzah, A. & Rahman, M.Y.A. 2010. Nanocomposite solid
polymeric electrolyte of 49% poly(methyl metacrylate)-grafted natural
rubber-titanium dioxide-lithium tetrafluroborate (MG49-TiO2-LiBF4). Journal
of Solid State Electrochem AIP: DOI:10.1007/ s10008-010-1252-0.
Makled,
M.H., Morri, K., Matsui, T., Mabuchi, H. & El-Mansy, M.K. 2005. Magnetic
and dynamic mechanical properties of barium ferrite-natural rubber
nanocomposites. Journal of Materials Processing Technology 160:
229-233.
Modak,
S., Ammar, M., Mazaleyrat, F., Das, F. & Chakrabarti, P.K. 2008. XRD, HRTEM
and magnetic properties of mixed spinel nanocrystalline Ni-Zn-Cu- ferrite. Journal
of Alloys and Compounds 473(1-2): 15-19.
Muhammad,
A.J.E., Joy, P.A., Kurian, P. & Anantharaman, M.R. 2009. Synthesis of
nickel-rubber nanocomposite and evaluation of their dielectric properties. Material
Science and Engineering B 156: 24-31.
PoZo
Lopez, G., Silvetti, S.P., Urreta, S.E. & Cabanillas, E.D. 2007. Magnetic
interactions in high energy ball-milled NiZnFe2O4/SiO2 composites. Physica B 398: 341-244.
Ramajo,
L.A., Cristobal, A.A., Botta, P.M., Porto Lopez, J.M., Reboredo, M.M. &
Castro, M.S. 2009. Dielectric and magnetic response of Fe3O4/epoxy composites. Composites:
Part A. 40: 388-393.
Wang
Chen, Lv Ruitao, Kang Feiyu, Gu Jialin, Gui Xuchun & Wu Dehai. 2009.
Sythesis and application of iron-filled carbon nanotubes coated with FeCo alloy
nanoparticles. Journal of Magnetism and Magnetic Materials 321(13):
1924-1927.
Youyi
Sun, Xing Zhao, Yaqing Liu, Guizhe Zhao & Yong Liang 2010. Effect of
magnetic nanoparticles on the properties of magnetic rubber. Materials
Research Bulletin 45: 878-881.
Xiao,
J., Otaigbe, J.U. & Jiles, D.C. 2000. Modeling of magnetic properties of
polymer bonded Nd-Fe-B magnets with surface modifications. Journal of
Magnetism Materials 218: 60-66.
Zhang
Lan, Zhu Hong, Song Yuan, Zhang Yongming & Huang Yi. 2008. The
electromagnetic characteristic and absorbing properties of multi-walled carbon
naotibes filled with Er2O3 nanoparticles as microwave
absorbers. Materials Science and Engineering B 153: 78-82.
*Corresponding
author; email: y_jiun@hotmail.com
|