Sains Malaysiana 43(3)(2014):
369–375
Trends in Sulfate Dry Deposition over Mixed Dipterocarp
Forest in Thailand using
Relaxed Eddy Accumulation Method
(Corak Pemendapan Kering Sulfat di atas Hutan Dipterokarpa Campuran
di Thailand
menggunakan Kaedah Akumulasi Eddy Santai)
KAN KHOOMSAB1*, POJANIE
KHUMMONGKOL1& KAZUHIDE
MATSUDA2
1Division of Environmental Technology, School of
Energy, Environment and Materials
King Mongkut's University of Technology Thonburi,
126 PrachaUthit Road, Bang Mod, Thungkhru, Bangkok 10140 Thailand
2Faculty of Agriculture Field Science Center, Tokyo University of
Agriculture and
Technology 3-5-8 Saiwai-cho, Fuchu, Tokyo 183-8509 Japan
Received: 9 October 2012/Accepted: 8 June 2013
ABSTRACT
The relaxed eddy accumulation method (REA) was applied for direct
measurement of sulfate fluxes over mixed dipterocarp forest. The
sampling system using a four-stage filter pack was designed to take
updraft or downdraft air samples in the direction of the vertical
wind velocity. The deadband of the velocity profile was set at ±0.5
σw in which an air sample with velocity within the
set value is rejected. The forest site was located at a latitude
of 13o 35'
13.3''N and longitude of 99o 30' 3.9''E Ratchaburi province in Thailand.
The sampling period was set in 4 time intervals: 6-12, 12-18, 18-24
and 24-6 h for 3 consecutive days/month (n=144) throughout one year.
All the micrometeorological parameters for flux estimation were
measured in real time. The concentration and flux of sulfate were
found to reach a peak value of 1.32 μg m-3 and
8.35 μg m-2
h-1, respectively, at noon time which indicated
the effect of atmospheric instability caused by a high heat transfer
during the day. The one-year average deposition velocity was observed
to be 0.24 cm s-1.The
coefficient β obtained under high ambient temperature and a
humid environment in this tropical climate was 0.49. It has also
been observed that βis relatively insensitive to atmospheric
stability.
Keywords: Dry deposition; forest; sulfate
ABSTRAK
Kaedah akumulasi eddy santai (REA) telah digunakan untuk
pengukuran langsung fluks sulfat di atas hutan dipterokarpa campuran.
Sistem pensampelan dengan menggunakan satu pek penapis empat peringkat
telah direka untuk mengambil sampel udara draf atas atau bawah yang
bergerak dalam arah halaju angin menegak. Paras akhir bagi profil
halaju ditetapkan pada ±0.5 σw dan sampel udara dengan halaju di bawah nilai yang
ditetapkan adalah ditolak. Tapak hutan tersebut terletak di kedudukan
latitud 13o 35' 13.3''N dan longitud 99o 30' 3.9'' E di wilayah
Ratchaburi, Thailand. Tempoh persampelan telah dijalankan dalam
4 selang masa: 6-12, 12-18 , 18-24 dan 24-6 jam dalam 3 hari berturut-turut
/bulan (n=144) dalam tempoh masa satu tahun. Semua parameter meteorologi
mikro untuk anggaran fluks diukur dalam masa sebenar. Sulfat didapati
mencapai paras puncak pada kepekatan dan fluks 1.32 μg m-3 dan 8.35 μg m-2 jam-1 masing-masing pada waktu
tengahari yang menunjukkan kesan ketidakstabilan atmosfera disebabkan
perpindahan haba yang tinggi pada waktu siang. Purata satu tahun
kelajuan pemendapan didapati adalah 0.24 cm s-1. Koefisien β yang diperoleh dalam
keadaan suhu ambien yang tinggi dan humiditi dalam iklim tropika
adalah 0.49. Hasil kajian juga mendapati βis secara relatif
tidak sensitif terhadap kestabilan atmosfera.
Keywords: Hutan; pemendapan kering; sulfat
REFERENCES
Acid Deposition Monitoring Network in East Asia. 2000. Quality
Assurance/Quality Control (QA/QC) Program for Monitoring on Inland Aquatic
Environment in East Asia. Report The Second Interim Scientific Advisory
Group Meeting of Acid Deposition Monitoring Network in East Asia.
Atkins, D.H.F. & Garland, J.A. 1974. The measurement of
deposition velocities for SO2 and particulate material by gradient method.
WMO special environment report No.3, Observation and Measurement of
Atmospheric Pollutions. WMO 368 Geneva. 579-594.
Businger, J.A. & Oncley, S.P. 1990. Flux measurement
with conditional sampling, J. Atmos. Oceanic. Tech. 7: 349–352.
Desjardins, R.L. 1972. A study of carbon – dioxide and
sensible heat fluxes using the eddy correlation technique. PhD dissertation.
Cornell University. USA (unpublished).
Doran, J.C. & Droppo, J.G. 1983. Profiles of elements in
the surface boundary layer. In Precipitation Scavenging Dry Deposition and
Resuspension, edited by Pruppacher, H.R., Semonin, R.G. & Slinn, W.G.N.
l 2: 1003-1012.
Driscoll, C.T., Driscoll, K.M., Mitchell, M.J. & Raynal,
D.J. 2003. Effects of acidic deposition on forest and aquatic ecosystems in New
York State. Environmental Pollution 123: 327-336.
Duyzer, J., Weststrate, H., Beswick, K. & Gallagher,
M.W. 1994. Measurements of the dry deposition flux of sulphate and nitrate
aerosols to the speulderbos using micrometeorological methods. Report
No.MW-R94/255. Energieonderzoek Centrum Nederland (ECN).
Everett, R.G., Hicks, B.B., Berg, W.W. & Winchester,
J.W. 1979. An analysis of particulate sulphur and lead gradient data collected
at Argonne Nation Laboratory. Atmospheric Environment 13: 931-934.
Fotiadi, A.K., Lohou, F., Druilhet, A., Serc, D.A., Said,
F., Laville, P. & Brut, A. 2005. Methodological development of the
conditional sampling method. Part II: Quality control criteria of relaxed eddy
accumulation flux measurements. Boundary-Layer Meteorology 117: 577-603.
Gaman, A., Rannik, Ü., Aalto, P., Pohja, T., Siivola, E.,
Kulmala, M. & Vesala, T. 2004. Relaxed eddy accumulation system for
size-resolved aerosol particle flux measurements. J. Atmos. Ocean. Tech.
21: 933-943.
Graus, M., Hansel, A., Wisthaler, A., Lindinger, C., Forkel,
R., Hauff, K., Klauer, M., Pfichner, A., RappenglÜck, B., Steigner, D. &
Steinbrecher, R. 2006. A relaxed-eddy-accumulation method for the measurement
of isoprenoid canopy-fluxes using an online gas-chromatographic technique and PTR-MS
simultaneously. Atmospheric Environment 40: 43-54.
GrÖnholm, T., Pasip, A., Veijo, H., Ullarr, R., Janne,
R., Lauri, L., Saara, H., Timo, V. & Markku, K. 2007. Measurements of aerosol particle dry
deposition velocity using the relaxed eddy accumulation technique.
Tellus 59B: 381-386.
GrÖnholm, T., Haapanala, S., Launiainen, S., Rinne, J.,
Vesala, T. & Rannik, Ü. 2008. The dependence of the β coefficient of
REA system with dynamic deadband on atmospheric conditions. Environmental
Pollution 152: 597-603.
Haapanala, S., Rinne, J., Pystynen, K-H., Hell´en, H. &
Hakola, H. 2005. Measurements of hydrocarbon emissions from a boreal fen using
the REA technique. Biogeosciences Discussions 2: 1645-1664.
Hamotani, K., Yohei, U., Nobutaka, M. & Akira, M. 1996.
A system of the relaxed eddy accumulation method to evaluate CO2 flux over
plant canopies. J. Agric. Meteorol. 52(2): 135-139.
Hazi, Y., Heikkinen, M.S.A. & Cohen, B.S.
2003. Size distribution of acidic sulfate ions in fine ambient particulate
matter and assessment of source region effect. Atmospheric Environment 37:
5403-5413.
Held, A., Edward, P., Luciana, R., Jim, S.,
Andrew, T. & Alex, G. 2008. Relaxed eddy accumulation simulations of
aerosol number fluxes and potential proxy scalars. Boundary – Layer
Meteorol. 129: 451-468.
Hicks, B.B., Wesely, M.L., Durham, J.L. &
Brown, M.A. 1982. Some direct measurements of atmospheric sulfur fluxes over a
pine plantation. Atmospheric Environment 16: 2899-2903.
Hicks, B.B. & McMillen, R.T. 1984. A
simulation of the eddy accumulation method for measuring pollutant fluxes. J.
Climate Appl. Meteorol. 23: 637-643.
Hicks, B.B., Matt, D.R., McMillen, R.T., Womack,
J.D., Wesely, M.L., Hart, R.L., Cook, D.R. Lindberg, S.E., De Pena, R.G. &
Thomson, D.W. 1989. A field investigation of sulfate fluxes to a deciduous
forest. Journal of Geophysical Research 94(D10): 13003-13011.
Katul, G., Finkelstein, P.L., Clark, J.F. &
Ellestad, T.G. 1996. An investigation of the conditional sampling methods used
to estimate fluxes of active, reactive, and passive scalars. J. Appl.Meteor. 35: 1835-1845.
Khoomsab, K. & Pojanie, K. 2010. Monitoring
of sulfate and nitrate fluxes above tropical forest using aerodynamic gradient
method. International Conference on Environment 2010 (ICENV 2010), Malaysia.
Lamaud, E., Chapus, A., Fontan, J. & Serie,
E. 1994. Measurements and parameterization of aerosol dry deposition in semi
– arid area. Atmospheric Environment 28: 2461-2471.
Lee, A., Schade, G.W., Holzinger, R. &
Goldstein, A.H. 2005. A comparison of new measurements of total monoterpene
flux with improved measurements of speciated monoterpene flux. Atmos. Chem.
Phys. 5: 505-513.
Lindroos, A.J., Derome, J., Derome, K. &
Lindgren, M. 2006. Trends in sulphate deposition on the forests and forest
floor and defoliation degree in 16 intensively studied forest stands in Finland
during 1996–2003. Boreal. Env. Res. 11: 451-461.
Matsuda, K., Yoshifumi, F., Kentaro, H., Akira,
T. & Ko, N. 2010. Deposition velocity of PM2.5 in the summer above a deciduous
forest in central Japan. Atmospheric Environment 44: 4582-4587.
Meyer, T.P., Luke, W.T. & Meisinger, J.J.
2006. Fluxes of ammonia and sulfate over maize using relaxed eddy accumulation. Agricultural and Forest Meteorology 136: 203-213.
Myles, L.T., Tilden, P.M. & Larry, R. 2007.
Relaxed eddy accumulation measurements of ammonia, nitric acid, sulfur dioxide
and particulate sulfate dry deposition near Tampa, FL, USA. Environ. Res.
Lett. 2: 1-8.
Monteith, J.L. & Mike, H.U. 2008.
Principle of Environmental Physics. USA: Elsevier Inc.
Mortimer, T. 2009. Acid Rain: The Effects.
Report Senior Project Social Sciences Department, College of Liberal Arts
California Polytechnic State University. USA.
Nemitz, E., Sutton, M.A., Wyers, G.P., Otjes,
R.P., Schjoerring, J.K., Gallagher, M.W., Parrington, J., Fowler, D. &
Choularton, T.W. 2000. Surface/atmosphere exchange and chemical interaction of
gases and aerosols over oilseed rape. Agric. Forest. Meteorol. 105:
427-445.
Odabasi, M. & Bagiroz, H.O. 2002. Sulfate
dry deposition fluxes and overall deposition velocities measured with a
surrogate surface. Sci. Total. Environ. 297(1-3): 193-201.
Olofsson, M., Ek-Olausson, B., Jensen, N.O.,
Langer, S. & LjungstrÖm, E. 2005. The flux of isoprene from a willow plantation
and the effect on local air quality. Atmospheric Environment 39:
2061-2070.
Pryor, S.C., Larsen, S.E., Sorensen, L.L. &
Barthelmie, R.J. 2008. Particle fluxes above forest: Observations,
methodological considerations and method comparisons. Environmental
Pollution 152: 667-678.
Ren, X., Sanders, J.E., Rajendran, A., Weber,
R.J., Goldstein, A.H., Pusede, S.E., Browne, E.C., Min, K.E. & Cohen, R.C.
2011. A relaxed eddy accumulation system for measuring vertical fluxes of
nitrous acid. Atmos. Meas. Tech. Discuss. 4: 4105-4130.
Seinfeld, J.H. & Pandis, S.N. 2006. Atmospheric
Chemistry and Physics: From Air Pollution to Climate Change. 2nd ed. New
York: John Wiley.
Skov, H., Brooks, S.B., Goodsitea, M.E.,
Lindbergb, S.E., Meyers, T.P., Landis, M.S., Larson, M.R.B., Jensen, B.,
McConvillee, G. & Christensen, J. 2006. Fluxes of reactive gaseous mercury
measured with a newly developed method using relaxed eddy accumulation. Atmospheric
Environment 40: 5452-5463.
Tasdemir, Y. & Gunez, H. 2006. Ambient concentration,
dry deposition flux and overall deposition velocities of particulate sulfate
measured at two sites. Atmospheric Research 81: 250-264.
Wesely, M.L., Cook, R., Hart, R.L. & Speer,
R.E. 1985. Measurements and parameterizations of particulate sulfur dry
deposition over grass. J. Geophys. Res. 90: 2131-2143.
Wyers, G. & Duyzer, J. 1997.
Micrometeorological measurement of dry deposition flux of sulfate and nitrate
aerosols to coniferous forest. Atmospheric Environment 31: 333-343.
Zemmelink, H.J., Gieskes, W.W.C., Klaassen, W.,
de Baar, H.W.J., Dacey, J.W.H., Hintsa, E.J. & McGillis, W.R. 2002.
Simultaneous use of relaxed eddy accumulation and gradient flux techniques for
the measurement of sea-to-air exchange of dimethyl sulfide. Atmospheric
Environment 36: 5709-5717.
*Corresponding author; email: topkan13@hotmail.com
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